Relationship between chloride and electrical conductivity

relationship between chloride and electrical conductivity

easier than determining chloride ion, the aim of this study was to develop an empirical relationship between chloride ion concentration and electrical conductivity. Conductivity is a measure of water's capability to pass electrical flow. The major ions in seawater (with a practical salinity of 35) are: chloride, The practical salinity scale is considered accurate for values between 2 and 42 psu a true mass fraction, and it ensures that all thermodynamic relationships ( density, sound. The electrical conductivity (EC) of a solution the relationship between EC and TDS commonly used is: ) . Na(K)Mg-chloride stream water type, and in.

The metal assumes a positive charge and is a cation whereas the nonmetal assumes a negative charge and is an anion.

relationship between chloride and electrical conductivity

Chemists refer to such salts as ionic compounds. Electrostatic interactions, which simply refers to the attractive forces between the oppositely charged metal and nonmetal, hold ionic compounds together as solids.

Conductivity Vs. Concentration | Sciencing

Ionic Compounds in Water Some ionic compounds are water-soluble, which means they dissolve in water. When these compounds dissolve, they dissociate, or break into their respective ions.

Table salt, also called sodium chloride and abbreviated NaCl, dissociates into sodium Na ions and chloride Cl ions. Not every ionic compound dissolves in water. Solubility guidelines provide chemists and students a general understanding of which compounds will dissolve and which compounds will not dissolve. Sciencing Video Vault Concentration of a Substance In basic terms, concentration simply refers to the amount of substance dissolved in a given amount of water.

Scientists use various units for specifying concentration, such as molarity, normality, mass percent and parts per million. The exact unit of concentration runs secondary, however, to the general principle that higher concentration means a larger quantity of dissolved salt per unit volume. Electrical Conductivity Many people are surprised to learn that pure water is actually a poor conductor of electricity. Good conductors allow for the easy, sustained flow of electric current.

Conductivity, Salinity & Total Dissolved Solids

Then, EC was estimated as the inverse of Rw. Finally, the chloride ion concentration was determined by the equation mentioned above.

Following the same procedure for the five remaining VESs, which were acquired in places where there are no wells, the chloride ion concentration and the electrical resistivity of the saturated formation Ro and groundwater Rw and its inverse EC were obtained without requiring a destructive technique. Archie's Law, chlorides, electrical conductivity, resistivity, vertical electrical sounding VES.

Introduction In saline soils, excess ions frequently include chlorides, sulphates, bicarbonates, sodium, calcium and magnesium.

relationship between chloride and electrical conductivity

The effects from the presence of all these ions on plant growth are generally evaluated by comparing the reaction of plants growing in isosmotic solutions of different salts. A generalization of the toxic effect of salts and ions is not possible due to the different responses among species and even among varieties of the same plant species Richards, In the United States, aquifers prone to seawater intrusion are characterized by chloride contents in concentrations between 5 and mg L-1, whereas the average concentration in contaminated wells in the Philippines is mg L The levels of chloride in non-contaminated waters are frequently lower than 10 mg L-1 and sometimes lower than 1 mg L-1 WHO, Chlorides are considered important in the nutritional balance of plants, and there is a frequent and remarkable lack of this chemical element.

The effects of chlorides on the control of root and foliar diseases in some crops such as wheat and barley also benefit vegetal nutrition Crovetto, However, excessive chloride accumulation damages the leaves of fruit trees, such as avocado, almond, papaya, sapote, mango, cherimoya, vitis, walnut and citrus trees.

The toxic level of chlorine accumulation in leaves is not yet well defined, as leaves showing burn damage may have a lower chlorine accumulation than leaves not showing it Aceves, The degree of ion chloride restriction Cl- in irrigation water with concentrations lower than 4 meq L-1 is considered light, between 4 and 10 meq L-1 is moderate, and concentrations higher than 10 meq L-1 are considered severe.

The maximum limit is 30 meq L-1 Palacios et al.

Conductivity, Salinity & Total Dissolved Solids - Environmental Measurement Systems

Water electrical conductivity EC is usually used as a salinity indicator. The presence of dissolved salts in water is related to the value of its EC, as they provide electrical charges interacting as ions in movement. EC can be easily measured by a conductivity meter. The chloride concentration is normally measured by silver nitrate titration AgNO3although this type of analysis is more expensive and takes longer than EC measurements.

Chloride ions are the main constituents in waters and saline soils that directly affect the EC values; therefore, it is possible to find a strong correlation between EC and Cl- concentrations, as found by many authors Oteri, ; Hajrasuliha et al, ; Xu and Eckstein, ; McNeil and Cox, ; Abyaneh et al.

However, Abyaneh et al. Many studies have used the Cl- concentration in the underground water to define the degree of saline intrusion. Some authors state that a threshold of chloride concentration ranging between 40 and mg L-1 is an indication of seawater invasion Edet and Okereke, Likewise, empirical relations between EC and soil and water salinity expressed in the same equation have been obtained Reluy et al.

Additionally, water electrical resistivity inverse to EC is related to the electrical resistivity of the saturated aquifer thickness Rowhich may be estimated by electrical methods of geophysical prospecting through Vertical Electrical Soundings VESs Keller and Frischknecht, The VES survey, supported by geological information, is an essential tool in hydrogeological studies, as it allows the characterization of large extensions in a short time at reasonable costs.

The high resistive contrast among the formations involved allows the unit limits to be clearly defined and the degree of pore water mineralization and layer thickness to be estimated Sosa and Palazzo, VESs and hydrochemical data have been used to examine the degree of intrusion of salt water in aquifers Edet and Okereke, ; Kouzana et al.

When the materials are not clean sands, the calculated formation factor is called the apparent formation-factor Fa. Several authors Norzagaray-Campos et al. The region is formed by a landscape composed of a smooth relief closely related to the origin and nature of the rocks' formation. The oldest rocks composing the geological basement are made up of shales and cherts. Tuff and sandstone formations and stratified and cemented conglomerates overlie these rocks. The subsoil plain was formed by a large sediment accumulation, reaching thicknesses greater than meters in the central valley and diminishing toward the Western Sierra Madre.

The current delta plain is composed of gravel, sands, silt and clay deposited in deltas CNA, The static aquifer water level in the area varies between 0.

This study aims to generate a tool for estimating the chloride concentration in the underground water of the Guasave region, Sinaloa, Mexico, using subsoil resistivity values obtainned from VES method, and the relation between the EC and the chloride concentration in the water based on the statistical analysis of the parameters obtained in wells. Materials and methods A total of 1, water well samples from different locations of the Guasave municipality were used to determine the Cl- and EC concentrations.

From the total analyzed samples, 66 were collected and analyzed in Octobercorresponding to wells for domestic use; 44 correspond to the western portion of the Sinaloa river and 12 to the eastern portion Figure 1.

The water samples correspond to the aquifer formation, as they were obtained during the pumping of the wells. Twenty-nine of the VES arrays were placed near a well, contrasting the values of the subsoil resistivity with the characteristics of the aquifer water electrical conductivity and chloride concentration.

The five remaining VESs were performed at sites without wells to verify the applicability of the method. The subsoil resistivity can be obtained from field data; therefore, it is assumed that the subsoil is stratified in horizontal, homogeneous and isotropic layers in regard to the electrical resistivity Orellana, In other words, the VESs allow readings of electrical currents and voltage differences in the field.

These readings are transformed into apparent electrical resistivity values, providing the true electrical resistivity of the subsoil by inverse numeric modeling methods assuming the geological medium composed of horizontal, homogeneous and isotropic layers.

relationship between chloride and electrical conductivity

The theoretical solution of this problem consists in solving the Laplace equation with boundary conditions. The data on apparent resistivity from each VES collected in the field were modeled with the program Resix-Plus version 1. The resistivity Ro of saturated thickness is obtained by modeling the processing of VES and correlating it with pore water resistivity Rw by a linear function. Models of linear, polynomial and potential regression were used to relate the EC with the Cl- concentration.

Seven 4 m-deep drills were made to colect soil samples. The subsoil samples were extracted at different depths and were subject to a drying and homogenization process to determine their texture silts, sands and clay content by the Bouyoucos method. Results and discussion The lateral and vertical variation of sediment can be observed from the profile traced in the study area. Figure 2 shows that the presence of clays in the featured section is relatively low compared with the concentrations of silt and sand; such material saturated with slightly brackish or brackish water satisfies the conditions for the application of Archie's Law.

As result of VES interpretation process, the resistivity and thickness values of the aquifer layer were obtained.

relationship between chloride and electrical conductivity

The model obtained for VES 1 is illustrated in Figure 3 along with corresponding data of apparent resistivity.